Container and composition for enhanced gas barrier properties

ABSTRACT

A container comprising a polyester composition with enhanced carbon dioxide and oxygen barrier properties is provided. The polyester composition comprises a polyester and a purine derivative. In a particular embodiment, the purine derivative comprises a purine dione, such as caffeine.

RELATED APPLICATION DATA

The present application claims priority under 35 U.S.C. § 119(e) to U.S.Provisional Application No. 60/723,751, entitled “Container andComposition for Enhanced Gas Barrier Properties,” filed on Oct. 5, 2005,which is hereby incorporated by reference in its entirety.

FIELD OF THE INVENTION

This invention relates to a packaged beverage, and more particularly toenhancing the carbon dioxide and oxygen barrier properties of acontainer for a packaged beverage, thereby increasing the shelf life ofits contents, by incorporating an additive into polyethyleneterephthalate (PET) and its copolyesters.

BACKGROUND AND OF THE INVENTION

Polyethylene terephthalate and its copolyesters (hereinafter referred tocollectively as “PET”) are widely used to make containers for carbonatedsoft drinks, juice, water, and the like due to their excellentcombination of clarity, mechanical, and gas barrier properties. In spiteof these desirable characteristics, insufficient gas barrier of PET tooxygen and carbon dioxide limits application of PET for smaller sizedpackages, as well as for packaging oxygen sensitive products, such asbeer, juice, and tea products. A widely expressed need exists in thepackaging industry to further improve the gas barrier properties of PET.

The relatively high permeability of PET to carbon dioxide limits the useof smaller PET containers for packaging carbonated soft drinks. Thepermeation rate of carbon dioxide through PET containers is in the rangeof 3 to 14 cc's per day or 1.5 to 2 percent per week loss rate at roomtemperature depending on the size of the container. A smaller containerhas a larger surface area to volume ratio resulting in a higher relativeloss rate. For this reason, PET containers are currently used only aslarger containers for packaging carbonated soft drinks, while metal cansand glass containers are the choice for smaller carbonated soft drinkcontainers.

The amount of carbon dioxide remaining in a packaged carbonated softdrink determines its shelf life. Normally, carbonated soft drinkcontainers are filled with approximately four volumes of carbon dioxideper volume of water. It is generally accepted that a packaged carbonatedsoft drink reaches the end of its shelf life when 17.5 percent of thecarbon dioxide in the container is lost due to permeation of the carbondioxide through the container side wall and closure. The permeability ofPET to carbon dioxide therefore determines the shelf life of thepackaged carbonated beverage and thus, the suitability of PET as apackaging material.

Numerous technologies have been developed or are being developed toenhance the barrier of PET to small gas molecules. For example, externalor internal coatings for enhancing the gas barrier of PET containershave been developed. The coating layer is normally a very high barrierlayer, either inorganic or organic, and slows down the diffusion ofgases. Implementation of this technology, however, requires coatingequipment not normally utilized in the manufacture of packaged beveragesand therefore requires substantial capital investment, increased energyusage, and increased floor space. In many beverage packaging plants thatare already crowded, the additional space is not an option.

Multi-layered containers have also been developed with a high barrierlayer sandwiched between two or more PET layers. Implementation of thistechnology also requires substantial capital investment and delaminationof the container layers impacts appearance, barrier, and mechanicalperformance of the containers.

A barrier additive for the PET or a polymer with inherent barrierproperties would be preferred solutions. Neither such solution requiresadditional capital investment, and therefore, does not have thelimitations inherent with other technologies. A barrier additive canalso be added during the injection molding process which gives moreflexibility for downstream operations.

L. M. Robeson and J. A. Faucher disclose in J. Polymer Science, Part B7, 35-40 (1969) that certain additives can be incorporated into polymersto increase their modulus and gas barrier properties through anantiplasticization mechanism. This article discloses utilizing additiveswith polycarbonate, polyvinyl chloride, polyphenylene oxide, andpolythyelene oxide.

In WO 01/12521, Plotzker et al. propose the use of additives selectedfrom 4-hydroxybenzoates and related molecules to increase the gasbarrier properties of PET. This published patent application disclosesbarrier additives of the following structure:

HO-AR-COOR, HO-AR-COOR COO-AR-OH, HO-AR-CONHR, HO-AR-CO-NHR3-COO-AR-OH,HO-AR-CONHR2NHCO-AR-OH

In the foregoing structure, AR is selected from the group consisting ofsubstituted or unsubstituted phenylene or naphthalene. And R₁, R₂, andR₃ are selected from the group consisting from C1 to C6 alkyl groups, aphenyl group, and a naphthyl group.

The foregoing additives described in the art provide only moderateimprovement in PET barrier, less than 2.1 times (X) for oxygen barrierfor the best examples with a 5 weight percent loading level. At thisloading level, however, PET experiences substantial degradation and asignificant drop in intrinsic viscosity (IV). Although lowering thelevel of additive reduces the degradation of PET, it also reduces thebarrier improvement factor, so much so that no real benefit exists inusing these additives in packaging carbonated soft drinks or oxygensensitive food. Part of the IV loss is due to the addition of the smallmolecular additive. Additional IV loss results when additives containfunctional groups capable of reacting with PET and causing the breakdown of the molecular weight. Additives with reactive functional groupsusually are more soluble in PET and thus do not impart haziness in thebottle. PET with a significantly lower IV cannot be used in blow moldingcontainers, such as beverage containers. Furthermore, lower IV PET makescontainers with poor mechanical performance, such as creep, drop impact,and the like, Still further, PET containers made from lower IV PET havepoor stress cracking resistance, which is undesirable in containerapplications.

PET has been modified or blended with other components to enhance thegas barrier of the PET. Examples include polyethylene naphthalate(PEN)/PET copolymers or blends, isophthalate (IPA) modified PET, PETblended with polyethylene isophthalate (PEI) or a polyamide, such asnylon, and PET modified with resorcinol based diols. For a PET copolymerto achieve moderate barrier enhancement of 2× or higher, themodification is normally more than 10 to 20 weight or mole percent ofthe total co-monomers. When PET is modified to such a high level, thestretching characteristics of the PET are changed dramatically such thatthe normal PET container preform design could not be used in themanufacture of containers. Using these PET copolymers to moldconventional PET container preforms results in preforms that can not befully stretched and the ultimate containers are very difficult, if notimpossible, to make. Even if such a container can be made, it does notshow improved barrier performance and shows deteriorated physicalperformance such that it can not be used to package carbonated softdrinks. U.S. Pat. Nos. 5,888,598 and 6,150,450 disclose redesigned PETcontainer preforms with thicker side walls to compensate for theincreased stretch ratio. This thicker preform, however, requires newmolds which require additional capital investment. The thicker preformis also made at a lower rate of productivity because it takes longer tocool and heat the thicker wall preform. Furthermore, PET blends withpolyamide such as nylon developed yellowness and haze and are not clearlike conventional PET.

Thus, there is a need in the art to enhance the barrier performance ofPET for use in applications that will require enhanced barrier, such asin the packaging of carbonated beverages and oxygen sensitive beveragesand foods, in a manner that does not cause substantial degradation ofthe PET, does not substantially impact the stretch ratio of the PET, anddoes not negatively impact the clarity of the PET.

SUMMARY OF THE INVENTION

This invention addresses the above-described needs by providing apolyester container with enhanced gas barrier properties comprising apolyester composition comprised of polyester and a purine derivative.

In accordance with a particular embodiment, the polyester in thepolyester composition comprises a poly(ethylene terethphalate) basedcopolymer (PET copolymer). In a particular embodiment, the polyestercomprises a PET copolymer having less than 20 percent diacid componentmodification and/or less than 10 percent diol component modification,based on 100 mole percent diacid component and 100 mole percent diolcomponent.

The polyester composition desirably comprises a purine derivative havingthe chemical structure of Formula I

wherein R₁, R₃, R₅, and R₇, independent of one another, comprise ahydrogen, arylamino, alkoxy, aryloxy, alkenyl, alkynyl, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group;

wherein t, t₁, x, x₁, x₂, y, and z, independent of one another, are asingle bond or a double bond; wherein t′, x′, y′, and z′, independent ofone another, are 0 or 1; wherein x″, y″, and w′, independent of oneanother, are 1 or 2;

wherein when x is a double bond, x₁ is a single bond; wherein when x₁ isa double bond, x and x₂ are single bonds; wherein when x₂ is a doublebond, x₁ and t₁ are single bonds; wherein when t is a double bond, t₁and z are single bonds; wherein when z is a double bond, t is a singlebond; wherein when t, is a double bond, t and x₂ are single bonds;wherein when x is a double bond, x′ is 0; wherein when x or x₁ is adouble bond, x″ is 1; wherein when y is a double bond, y′ is 0 and y″ is1; wherein when t or t₁ is a double bond, t′ is 0; wherein when z and tare single bonds, w′ is 2; wherein when z or t is a double bond, w′ is1; wherein when z is a double bond, z′ is 0; wherein when x, y, or z,independent of one another, is a single bond, and x′, y′, or z′,independent of one another, is 1;

wherein R₂, R₄, and R₆, independent of one another, may be moietiesattached by a single or double bond;

wherein when R₂, R₄, or R₆ is a moiety attached by a single bond, R₂, R₄and R₆, independent of one another, comprise a hydrogen, hydroxyl,amino, amido, alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl,alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto, imino, sulfonyl,sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl, phophoryl,phosphino, thioester, thioether, anhydride, oximno, hydrazino, carbamyl,phosphonic acid, phosphonato, or a straight, chained, branched, orcyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl, heterocyclic, or acylgroup;

wherein when R₂, R₄, or R₆ is a moiety attached by a double bond, R₂,R₄, or R₆, independent of one another, comprise oxygen, sulfur, CR₈R₉,SO₂, or NR₁₀; R₈ and R₉, independent of one another, comprise ahydrogen, hydroxyl, amino, amido, alkylamino, arylamino, alkoxy,aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto,imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl,phophoryl, phosphino, thioester, thioether, anhydride, oximno,hydrazino, carbamyl, phosphonic acid, phosphonato, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group; and R₁₀ comprises a hydrogen, arylamino,alkoxy, aryloxy, alkenyl, alkynyl, or a straight, chained, branched, orcyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl, heterocyclic, or acylgroup; and

wherein when x″ is 2, both R₂ moieties may be the same or different;wherein when y″ is 2, both R₄ moieties may be the same or different; andwherein when w′ is 2, both R₆ moieties may be the same or different.

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaII

wherein t₁, x, x₁, y, and z are single bonds; wherein x₂ and t aredouble bonds; wherein w′, x′, y′, z′, x″, and y″ are 1; wherein t′ is 0;wherein R₂ and R₄, independent of one another, are moieties attached bya double bond comprising oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; andwherein R₁, R₃, R₅, and R₆, independent of one another, comprise ahydrogen, hydroxyl, amino, amido, alkylamino, arylamino, alkoxy,aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto,imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl,phophoryl, phosphino, thioester, thioether, anhydride, oximno,hydrazino, carbamyl, phosphonic acid, phosphonato, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group.

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaIII

wherein x, x₁, y, and t, and t₁ are single bonds; wherein x₂ and z aredouble bonds; wherein t′, w′, x′, y′, x″, and y″ are 1; wherein z′ is 0;wherein R₂ and R₄, independent of one another, are moieties attached bya double bond comprising oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; andwherein R₁, R₃, R₆, and R₇, independent of one another, comprise ahydrogen, hydroxyl, amino, amido, alkylamino, arylamino, alkoxy,aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto,imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl,phophoryl, phosphino, thioester, thioether, anhydride, oximno,hydrazino, carbamyl, phosphonic acid, phosphonato, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group.

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaIV

wherein x, x₁, y, t, t₁, and z are single bonds; wherein X2 is a doublebond; wherein t′, w′, x′, y′, z′, x″, and y″ are 1; wherein R₂, R₄, andR₆, independent of one another, are moieties attached by a double bondcomprising oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₁, R₃, R₅,and R₇, independent of one another, comprise a hydrogen, hydroxyl,amino, amido, alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl,alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto, imino, sulfonyl,sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl, phophoryl,phosphino, thioester, thioether, anhydride, oximno, hydrazino, carbamyl,phosphonic acid, phosphonato, or a straight, chained, branched, orcyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl, heterocyclic, or acylgroup,

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaV

wherein x, x₁, t₁, and z are single bonds; wherein and x₂, t, and y aredouble bonds; wherein w′, x′, z′, x″, and y″ are 1; wherein y′ and t′are 0; wherein R₄ is a moiety attached by a double bond comprisingoxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₁, R₂, R₅, and R₆,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group.

In another embodiment, the purine derivative comprises a compound havingthe chemical structure of Formula VI

wherein x, x₂, y and z are double bonds; wherein x₁, t, and t₁ aresingle bonds; wherein t′, w′, x″, and y″ are 1; wherein x′, y′, and z′are 0; and wherein R₂, R₄, R₆, and R₇ comprise a hydrogen, hydroxyl,amino, amido, alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl,alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto, imino, sulfonyl,sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl, phophoryl,phosphino, thioester, thioether, anhydride, oximno, hydrazino, carbamyl,phosphonic acid, phosphonato, or a straight, chained, branched, orcyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl, heterocyclic, or acylgroup.

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaVII

wherein x, x₂, and t are double bonds; wherein t₁, x₁, y and z aresingle bonds; wherein w′, y′, z′, x″, and y′, are 1; wherein t′ and x′are 0; wherein R₂ is a moiety attached by a double bond comprisingoxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₃, R⁴, R₅, and R₆,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaVIII

wherein x₂, y and t are double bonds; wherein x, x₁, t₁, and z aresingle bonds; wherein w′, x′, z′, x″, and y″ are 1; wherein t′ and y′are 0; wherein R₄ is a moiety attached by a double bond comprisingoxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₁, R₂, R₅, and R₆,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group.

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaIX

wherein x₁, y, t₁, and z are double bonds; wherein x, x₂, and t aresingle bonds; wherein w′, x′, x″, and y″ are 1; wherein t′, y′, and z′are 0; and wherein R₁, R₂, R₄, and R₆, independent of one another,comprise a hydrogen, hydroxyl, amino, amido, alkylamino, arylamino,alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato,mercapto, imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl,phophinyl, phophoryl, phosphino, thioester, thioether, anhydride,oximno, hydrazino, carbamyl, phosphonic acid, phosphonato, or astraight, chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl,heteroaryl, heterocyclic, or acyl group.

According to another embodiment, this invention encompasses a method forenhancing gas barrier properties of a polyester container comprisingblending a polyester with a purine derivative to form a polyestercomposition. According to particular embodiments, the polyestercomposition can be formed into articles such as a container.

Furthermore, in another embodiment of the invention, the step of formingthe container comprises stretch blow molding. Particular embodiments ofthis invention provide polyester containers, such as PET containers,with enhanced gas barrier, and in particular, enhanced gas barrier tocarbon dioxide and oxygen. This makes certain embodiments of theinvention particularly suited for packaging carbonated soft drinks andoxygen sensitive beverages and foods. Particular embodiments achievethis enhanced gas barrier while maintaining acceptable physicalproperties and clarity.

Other objects, features, and advantages of the invention will beapparent from the following detailed description and claims.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a schematic diagram of a system for making a PET containerwith enhanced gas barrier in accordance with an embodiment of thisinvention.

FIG. 2 is a sectional elevation view of a molded container preform madein accordance with an embodiment of this invention.

FIG. 3 is a sectional elevation view of a blow molded container madefrom the preform of FIG. 2 in accordance with an embodiment of thisinvention.

FIG. 4 is a perspective view of a packaged beverage made in accordancewith an embodiment of this invention.

DETAILED DESCRIPTION OF THE INVENTION

This invention encompasses a polyester container with enhanced gasbarrier properties and a method for making a polyester container withenhanced gas barrier properties. Polyester containers and methods formaking such containers made in accordance with embodiments of thisinvention are further described below and in accompanying FIGS. 1-4.

I. Polyester Composition

This invention is applicable to any polyester and is suitable for usesin which a high gas barrier is desirable. Suitable polyesters for use inembodiments of this invention include PET copolymers, polyethylenenaphthalate (PEN), polyethylene isophthalate, and the like. PETcopolymers are particularly useful because they are used for manybarrier applications such as films and containers. Suitable containersinclude, but are not limited to, bottles, drums, carafes, coolers, andthe like.

PET copolymers suitable for use in embodiments of this inventioncomprise a diol component having repeat units from ethylene glycol and adiacid component having repeat units from terephthalic acid. Inparticular embodiments, the PET copolymer has less than 20 percentdiacid modification, 10 percent glycol modification, or both, based on100 mole percent diacid component and 100 mole percent diol component.Such PET copolymers are well known.

Polyesters, including PET copolymers, have free volume between thepolymer chains. As is known to those skilled in the art, the amount offree volume in polyesters such as PET copolymers determines theirbarrier to gas molecules. The lower the free volume, the lower the gasdiffusion, and the higher the barrier to gas molecules. Desirably, thegas barrier enhancing additive is at least partially disposed in thefree volume of the polyester between the polyester chains.

In a particular embodiment, a polyester composition comprises apolyester and an enhanced gas barrier additive comprising a purinederivative, which is further described below. The purine derivative ofthe polyester composition enhances the gas barrier properties of thepolyester composition at low loading levels, desirably in the range ofabout 0.2 to about 10 weight percent of the polyester composition, moredesirably in the range of about 3 to about 10 weight percent of thepolyester composition, and still more desirably in the range of about 3to about 5 weight percent of the polyester composition. At low loadinglevels, a slight barrier improvement factor (BIF) occurs, Although theimprovement in the BIF is substantial at high loading levels, thephysical properties of the PET deteriorate and make forming a containermore difficult. The BIF is a measure of enhanced gas barrier properties(the ratio of the gas transmission rate of a polyester compositionwithout an additive to the gas transmission rate of a polyestercomposition with an additive).

According to another embodiment, the polyester composition comprises:

a) a polyester present in the polyester composition in an amount in therange of about 90 to about 99.8 weight percent of the polyestercomposition; and

b) a purine derivative present in the polyester composition in an amountin the range of about 0.2 to about 10 weight percent of the polyestercomposition.

In a particular embodiment, the polyester comprises a poly(ethyleneterephthalate) based copolymer having less than 20 percent diacidmodification, 10 percent glycol modification, or both, based on 100 molepercent diacid component and 100 mole percent diol component.

In another particular embodiment, the purine derivative is present inthe polyester composition in an amount in the range of about 3 to about10 weight percent of the polyester composition. In another particularembodiment, the purine derivative is present in the polyestercomposition in an amount in the range of about 3 to about 5 weightpercent of the polyester composition.

II. Purine Derivatives

In a particular embodiment, a purine derivative has the chemicalstructure of Formula I

wherein R₁, R₃, R₅, and R₇, independent of one another, comprise ahydrogen, arylamino, alkoxy, aryloxy, alkenyl, alkynyl, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group;

wherein t, t₁, x, x₁, x₂, y, and z, independent of one another, are asingle bond or a double bond; wherein t′, x′, y′, and z′, independent ofone another, are 0 or 1; wherein x″, y″, and w′, independent of oneanother, are 1 or 2;

wherein when x is a double bond, x₁ is a single bond; wherein when x₁ isa double bond, x and x₂ are single bonds; wherein when x₂ is a doublebond, x₁ and t₁ are single bonds; wherein when t is a double bond, t₁and z are single bonds; wherein when z is a double bond, t is a singlebond; wherein when t₁ is a double bond, t and x₂ are single bonds;wherein when x is a double bond, x′ is 0; wherein when x or x₁ is adouble bond, x″ is 1; wherein when y is a double bond, y′ is 0 and y″ is1; wherein when t or t₁ is a double bond, t′ is 0; wherein when z and tare single bonds. w′ is 2; wherein when z or t is a double bond, w′ is1; wherein when z is a double bond, z′ is 0; wherein when x, y, or z,independent of one another, is a single bond, and x′, y′, or z′,independent of one another, is 1;

wherein R₂, R₄, and R₆, independent of one another, may be moietiesattached by a single or double bond;

wherein when R₂, R₄, or R₆ is a moiety attached by a single bond, R₂, R₄and R₆, independent of one another, comprise a hydrogen, hydroxyl,amino, amido, alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl,alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto, imino, sulfonyl,sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl, phophorl,phosphino, thioester, thioether, anhydride, oximno, hydrazino, carbamyl,phosphonic acid, phosphonato, or a straight, chained, branched, orcyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl, heterocyclic, or acylgroup;

wherein when R₂, R₄, or R₆ is a moiety attached by a double bond, R₂,R₄, or R₆, independent of one another, comprise oxygen, sulfur, CR₈R₉,SO₂, or NR₁₀; R₈ and R₉, independent of one another, comprise ahydrogen, hydroxyl, amino, amido, alkylamino, arylamino, alkoxy,aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto,imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl,phophoryl, phosphino, thioester, thioether, anhydride, oximno,hydrazino, carbamyl, phosphonic acid, phosphonato, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group; and R₁₀ comprises a hydrogen, arylamino,alkoxy, aryloxy, alkenyl, alkynyl, or a straight, chained, branched, orcyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl, heterocyclic, or acylgroup.

wherein when x″ is 2, both R₂ moieties may be the same or different;wherein when y″ is 2, both R₄ moieties may be the same or different; andwherein when w′ is 2, both R₆ moieties may be the same or different.

The moieties described above may further be substituted as known by oneskilled in the art with a hydrogen, halogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbarnyl, phosphonic acid,phosphonato, and any other viable functional group.

In one embodiment of the compound of Formula I, the purine derivativecomprises 7H-purine, having the chemical structure

wherein x, x₂, y, and t are double bonds; wherein x₁, t₁ and z aresingle bonds; wherein x′, y′, and t′ are 0; wherein x″, y″, z′, and w′are 1; and wherein R₂, R₄, R₅, and R₆ are hydrogen.

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaII

wherein t₁, x, x₁, y, and z are single bonds; wherein x₂ and t aredouble bonds; wherein w′, x′, y′, z′, x″, and y″ are 1; wherein t′ is 0;wherein R₂ and R₄, independent of one another, are moieties attached bya double bond comprising a oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; andwherein R₁, R₃, R₅, and R₆ independent of one another, comprise ahydrogen, hydroxyl, amino, amido, alkylamino, arylamino, alkoxy,aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto,imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl,phophoryl, phosphino, thioester, thioether, anhydride, oximno,hydrazino, carbamyl, phosphonic acid, phosphonato, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group, wherein the moieties may be furthersubstituted as described above,

In a particular embodiment of the compound of Formula II, the purinederivative comprises theobromine, a purine dione having the chemicalstructure

wherein R₁ and R₆ are hydrogen; wherein R₂ and R₄ are oxygen; andwherein R₃ and R₅ are methyl,

In another embodiment of the compound of Formula II, the purinederivative comprises caffeine, a purine dione having the chemicalstructure

wherein R₆ is hydrogen; R₂ and R₄ are oxygen; and R₁, R₃ and R₅ aremethyl.

In still another embodiment of the compound of Formula II, the purinederivative comprise theophylline, a purine dione having the chemicalstructure

wherein R₅ and R₆ are hydrogen; wherein R₂ and R₄ are oxygen; andwherein R₁ and R₃ and are methyl.

In still yet another embodiment of the compound of Formula II, thepurine derivative comprises xanthine, a purine dione having the chemicalstructure

wherein R₁, R₃, R₅ and R₆ are hydrogen: and R₂ and R₄ are oxygen.

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaIII

wherein x, x₁, y, and t, and t₁ are single bonds; wherein x₂ and z aredouble bonds; wherein t′, w′, x′, y′, x″, and y″ are 1; wherein z′ is 0;wherein R₂ and R₄, independent of one another, are moieties attached bya double bond comprising oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; andwherein R₁, R₃, R₆, and R₇, independent of one another, comprise ahydrogen, hydroxyl, amino, amido, alkylamino, arylamino, alkoxy,aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto,imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl,phophoryl, phosphino, thioester, thioether, anhydride, oximno,hydrazino, carbamyl, phosphonic acid, phosphonato, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group, wherein the moieties may be furthersubstituted as described above.

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaIV

wherein x, x₁, y, t, t₁, and z are single bonds; wherein x₂ is a doublebond; wherein t′, w′, x′, y′, z′, x″, and y″ are 1; wherein R₂, R₄, andR₆, independent of one another, are moieties attached by a double bondcomprising oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₁, R₃, R₅,and R₇, independent of one another, comprise a hydrogen, hydroxyl,amino, amido, alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl,alkenyl, alkynyl, cyano, sulfo, sulfato, mereapto, imino, sulfonyl,sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl, phophoryl,phosphino, thioester, thioether, anhydride, oximno, hydrazino, carbamyl,phosphonic acid, phosphonato, or a straight chained, branched, or cyclicalkyl, alkenyl, alkynyl, aryl, heteroaryl, heterocyclic, or acyl group,wherein the moieties may be further substituted as described above.

In a particular embodiment of the compound of Formula IV, the purinederivative comprises uric acid, a purine dione having the chemicalstructure

wherein R₁, R₃, R₅ and R₇ are hydrogen; and wherein R₂, R₄, and R₆ areoxygen.

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaV

wherein x, x₁, t₁, and z are single bonds; wherein and x₂, t, and y aredouble bonds; wherein w′, x′, z′, x″, and y″ are 1; wherein y′ and t′are 0; wherein R₄ is a moiety attached by a double bond comprisingoxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₁, R₂, R₅, and R₆,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group, wherein themoieties may be further substituted as described above.

In a particular embodiment of the compound of Formula V, the purinederivative comprises guanine, having the chemical structure

wherein R₁, R₅, and R₆ are hydrogen; wherein R₂ is amino; and wherein R₄is oxygen.

In another embodiment, the purine derivative comprises a compound havingthe chemical structure of Formula VI

wherein x, x₂, y and z are double bonds; wherein x₁, t, and t₁ aresingle bonds; wherein t′, w′, x″, and y″ are 1; wherein x′, y′, and z′are 0; and wherein R₂, R₄, R₆, and R₇ comprise a hydrogen, hydroxyl,amino, amido, alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl,alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto, imino, sulfonyl,sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl, phophoryl,phosphino, thioester, thioether, anhydride, oximno, hydrazino, carbamyl,phosphonic acid, phosphonato, or a straight, chained, branched, orcyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl, heterocyclic, or acylgroup, wherein the moieties may be further substituted as describedabove.

In a particular embodiment of the compound of Formula VI, the purinederivative comprises adenine, having the chemical structure

wherein R₂, R₆, and R₇ are hydrogen; and wherein R₄ is an amino.

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaVII

wherein x, x₂, and t are double bonds: wherein t₁, x₁, y and z aresingle bonds; wherein w′, y′, z′, x″, and y″ are 1; wherein t′ and x′are 0; wherein R₂ is a moiety attached by a double bond comprisingoxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₃, R₄, R₅, and R₆,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group, wherein themoieties may be further substituted as described above.

In a particular embodiment of the compound of Formula VII, the purinederivative comprises guanine, having the chemical structure

wherein R₃, R₅, and R₆ are hydrogen; wherein R₂ is oxygen; and whereinR₄ is amino.

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaVIII

wherein x₂, y and t are double bonds; wherein x, x₁, t₁, and z aresingle bonds; wherein w′, x′, z′, x″, and y″ are 1; wherein t′ and y′are 0; wherein R₄ is a moiety attached by a double bond comprisingoxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₁, R₂, R₅, and R₆,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group, wherein themoieties may be further substituted as described above.

In a particular embodiment of the compound of Formula VIII, the purinederivative comprises 7-methylguanine, having the chemical structure

wherein R₁ and R₆ are hydrogen; wherein R₂ is amino; wherein R₄ isoxygen, and wherein R₅ is methyl.

In another particular embodiment of the compound of Formula VIII, thepurine derivative comprises thioguanine, having the chemical structure

wherein R₁, R₅, and R₆ are hydrogen; wherein R₂ is amino; and wherein R₄is sulfur.

In yet another embodiment of the compound of Formula VIII, the purinederivative comprises 6-mercaptopurine, having the chemical structure

wherein R₁, R₂, R₅, and R₆ are hydrogen; and wherein R₄ is sulfur.

In still another embodiment of the compound of Formula VIII, the purinederivative comprises hypoxanthine, having the chemical structure

wherein R₁, R₂, R₅, and R₆ are hydrogen; and wherein R₄ is oxygen.

In another embodiment of the compound of Formula I, the purinederivative comprises a compound having the chemical structure of FormulaIX

wherein x₁, y, t₁, and z are double bonds; wherein x, x₂, and t aresingle bonds; wherein w′, x′, x″, and y″ are 1; wherein t′, y′, and z′are 0; and wherein R₁, R₂, R₄, and R₆, independent of one another,comprise a hydrogen, hydroxyl, amino, amido, alkylamino, arylamino,alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato,mercapto, imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl,phophinyl, phophoryl, phosphino, thioester, thioether, anhydride,oximno, hydrazino, carbamyl, phosphonic acid, phosphonato, or astraight, chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl,heteroaryl, heterocyclic, or acyl group, wherein the moieties may befurther substituted as described above.

In a particular embodiment of the compound of Formula IX, the purinederivative comprises 1H-purine, having the chemical structure

wherein R₁, R₂, R₄, and R₆ are hydrogen.

In another particular embodiment of the compound of Formula IX, thepurine derivative comprises diaminopurine, having the chemical structure

wherein R₁ and R₆ are hydrogen; and wherein R₂ and R₄ are amino.

The term “alkyl”, as used herein, unless otherwise specified, refers toa saturated straight, branched, or cyclic, primary, secondary, ortertiary hydrocarbon of C1 to C20, and specifically includes methyl,ethyl, propyl, isopropyl, butyl, isobutyl, t-butyl, pentyl, isopentyl,neopentyl, hexyl, and isohexyl. The term includes both substituted andunsubsituted alkyl groups. Moieties with which the alkyl group can besubstituted are selected from the group consisting of hydrogen, halogen,hydroxyl, amino, amido, alkylamino, arylamino, alkoxy, aryloxy, nitro,acyl, alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto, imino,sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl,phophoryl, phosphino, thioester, thioether, anhydride, oximno,hydrazino, carbamyl, phosphonic acid, phosphonato, and any other viablefunctional group.

The term “alkenyl”, as referred to herein, and unless otherwisespecified, refers to a straight, branched, or cyclic hydrocarbon of C2to C10 with at least one double bond. The alkenyl groups optionally canbe substituted in the same manner as described above for the alkyl groupand also optionally can be substituted with a substituted orunsubstituted alkyl group.

The term “alkynyl”, as used herein, and unless otherwise specified,refers to a C2 to C10 straight or branched hydrocarbon with at least onetriple bond. The alkynyl groups optionally can be substituted in thesame manner as described above for the alkyl groups and also optionallycan be substituted with a substituted or unsubstituted alkyl group.

The term “aryl”, as used herein, and unless otherwise specified, refersto any functional group or substituent derived from an aromatic ring.Non-limiting examples include phenyl, biphenyl, or napthyl. The termincludes both substituted and unsubstituted moieties. The aryl groupoptionally can be substituted with one or more moieties as describedabove for the alkyl groups or a substituted or unsubstituted alkylgroup.

The term “heteroaryl” or “heteroaromatic”, as used herein, refers to anaromatic or unsaturated cyclic moiety that includes at least one sulfur,oxygen, nitrogen, or phosphorus in the aromatic ring. Non-limitingexamples are furyl, pyridyl, pyrimidyl, thienyl, isothiazolyl,imidazolyl, tetrazolyl, pyrazinyl, benofuranyl, benothiophenyl,quinolyl, isoquinolyl, benzothienyl, ixobenzoiryl, pyrazolyl, indolyl,isoindolyl, benimidazolyl, purinyl, carbazolyl, oxazolyl, thiazolyl,isothiazolyl, 1,2,4-thiadiazolyl, isoxazolyl, pyrolyl, quinazolinyl,pyridazinyl, pyrazinyl, cinnolyl, phthalazinyl, quinoxalinyl, xanthinyl,hypoxanthinyl, and pteridnyl. The heteroaryl or heteroaromatic groupoptionally can be substituted with one or moieties as described abovefor the alkyl group or a substituted or unsubstituted alkyl group.

The term “heterocyclic” refers to a saturated nonaromatic cyclic groupwhich optionally may be substituted, and wherein there is at least oneheteroatom or non-carbon atom, such as oxygen, sulfur, nitrogen, orphosphorus in the ring. The heterocyclic group optionally can besubstituted in the same manner as described above for the heteroarylgroup.

The term “aralkyl”, as used herein, and unless otherwise specified,refers to an aryl group as defined above linked to the molecule throughan alkyl group as defined above. The term alkaryl, as used herein, andunless otherwise specified, refers to an alkyl group as defined abovelinked to the molecule through an aryl group as defined above. Thearalkyl or alkaryl group optionally can be substituted with one or moremoieties selected from the group consisting of hydroxyl, carboxy,carboxamido, carboalkoxy, acyl, amino, halo, alkylamino, alkoxy,aryloxy, nitro, cyano, sulfo, sulfato, phospho, phosphato, andphosphonato.

The term “halo”, as used herein, specifically includes chloro, bromo,iodo, and fluoro.

The term “alkoxy”, as used herein, and unless otherwise specified,refers to a moiety of the structure —O-alkyl, wherein alkyl is asdefined above.

The term “acyl”, as used herein, refers to a group of the formulaC(O)R′, wherein R′ is an alkyl, aryl, heteroaryl, heterocyclic, alkarylor aralkyl group, or substituted alkyl, aryl, heteroaryl, heterocyclic,aralkyl or alkaryl, wherein these groups are as defined above.

II. Methods of Making Polyester Composition and Containers

As described above, the polyester composition of this invention isuseful for making containers in which enhanced gas barrier is desirable.In short, such containers are made by forming the above describedpolyester compositions into the desired container by conventionalmethods such as melt forming. Suitable melt forming processes include,but are not limited to, injection molding, extrusion, thermal formingand compression molding. The particularly preferred method for makingthe containers of this invention is stretch blow molding.

Methods for incorporating the purine derivative additive into thecontainer and polyester composition are also provided herein. Suchmethods also well known to those skilled in the art. For example, anadditive can be fed directly into the polyester during the injectionmolding process, preblended with the polyester resin prior to injectionmolding, or incorporated at high concentrations with PET as masterbatchand then blended with the polyester resin prior to injection molding ofthe container.

FIG. 1 illustrates a system 10 in accordance with an embodiment of thisinvention for making a rigid container preform 12 (illustrated in FIG.2) and a rigid container 14 (illustrated in FIG. 3) from the preform. Asis shown in FIG. 1, PET 20 and a gas barrier enhancing additive 22, suchas a purine derivative, are added to a feeder or hopper 24 that deliversthe components to a hot melt extruder 26 in which the components aremelted and blended. The hot melt extruder 26 then extrudes the moltenmixture of PET 20 and gas barrier enhancing additive 22 into aninjection molding device 28 to form the preform 12. The preform 12 iscooled and removed from the injection molding device 28 and delivered toa stretch blow molding device 30 which stretch blow molds the preform 12into a finished rigid container 14.

The melt residence time of the preform production is preferably lessthan five minutes and more preferably from about one to about threeminutes. The melt temperatures are desirably from about 270 to about300° C. and more desirably from about 270 to about 290° C. The meltresidence time begins when the PET 20 and gas barrier enhancing additive22 enter the melt extruder 26 and start melting, and ends afterinjection of the molten blend into the injection mold to form thepreform 12.

In a particular embodiment, the injection molding process can bemodified by pressurizing the mold cavity to minimize plate-out, asdescribed in the co-pending U.S. patent application entitled“Pressurized Tooling for Injection Molding and Method of Using,” whichis hereby incorporated by reference in its entirety, and was filed onSep. 15, 2006, by Schultheis, et al. Pressurizing the mold cavitychanges the dynamics of the processing cycle by reducing or completelyeliminating the ability of additives to diffuse through the PETcopolymer and deposit on the inner surface of the mold. The desiredpressure of the mold cavity can be optimized for a particular polymermaterial, polymer matrix, or additive.

The modified injection molding process (not pictured) includes theadditional step of pressurizing a mold by introducing a pressurized gasinto a mold cavity in the mold, wherein the mold cavity defines theshape of the container preform; introducing a polyester composition intothe mold cavity; cooling the polyester composition to form the containerpreform; and removing the container preform from the mold cavity.

The pressurized gas may be any gas that does not detrimentally affectthe polyester composition. Non-limiting examples include air and itsindividual components, oxygen, nitrogen, and carbon dioxide; the noblegases, argon, neon, helium, and xenon; and mixtures thereof. In aparticular embodiment, the mold cavity is pressurized to a pressure inthe range of about 1 to about 1000 psig.

III. Containers

As is well known to those skilled in the art, containers can be made byblow molding a container preform. Examples of suitable preform andcontainer structures are disclosed in U.S. Pat. No. 5,888,598, thedisclosure of which is expressly incorporated herein by reference in itsentirety.

A polyester container preform 12 is illustrated in FIG. 2. This preform12 is made by injection molding PET based resin and comprises a threadedneck finish 112 which terminates at its tower end in a capping flange114 Below the capping flange 114, there is a generally cylindricalsection 116 which terminates in a section 118 of gradually increasingexternal diameter so as to provide for an increasing wall thickness.Below the section 118 there is an elongated body section 120.

The preform 12 illustrated in FIG. 2 can be stretch blow molded to forma container 14 illustrated in FIGS. 3 and 4. The container 14 comprisesa shell 124 comprising a threaded neck finish 126 defining a mouth 128,a capping flange 130 below the threaded neck finish, a tapered section132 extending from the capping flange, a body section 134 extendingbelow the tapered section, and a base 136 at the bottom of thecontainer. The container 14 is suitably used to make a packaged beverage138, as illustrated in FIG. 4. The packaged beverage 138 includes abeverage such as a carbonated soda beverage disposed in the container 14and a closure 140 sealing the mouth 128 of the container.

The polyester container optionally may comprise a plurality of layers asdescribed in co-pending patent application No. ______, filed on Sep. 15,2006, entitled “Multilayer Container having Small Molecule BarrierAdditives,” the disclosure of which is expressly incorporated herein byreference in its entirety. A multilayer container can permit the use ofadditives in a barrier layer that normally would be too volatile forinclusion in a single layer container because the low molecular weightadditive is contained within two outer layers without the low molecularweight additive, preventing contact between the low molecular weightadditive and the surfaces of the injection molding apparatus.

Briefly described, a multilayer container comprises at least two outerlayers comprising a polymer matrix and at least one barrier layerdisposed between the at least two outer layers. The at least one barrierlayer comprises a polyester composition comprising a polyester and anenhanced gas barrier additive comprising a purine derivative. Desirably,the low molecular weight additive is present in the multilayer containerin an amount in the range of about 0.2 to about 10 weight percent of thecontainer, the at least two outer layers comprise about 99 to about 20weight percent of the container, and the one or more barrier layerscomprise about 1 to about 80 weight percent of the container. In anotherparticular embodiment, the multilayer container further comprises atleast one intermediate layer between the at least one barrier layer andthe at least two outer layers.

The preform 12, container 14, and packaged beverage 138 are but examplesof applications using the preforms of the present invention. It shouldbe understood that the process and apparatus of the present inventioncan be used to make preforms and containers having a variety ofconfigurations.

The present invention is further illustrated by the following examples,which are not to be construed in any way as imposing limitations uponthe scope thereof. On the contrary, it is to be clearly understood thatresort may be had to various other embodiments, modifications, andequivalents thereof which, after reading the description therein, maysuggestion themselves to those skilled in the art without departing fromthe spirit of the present invention and/or the scope of the appendedclaims.

EXAMPLES Example 1

A commercially available polyester container grade resin (Kosa,Spartanburg, S.C.) was dried in a vacuum oven at 140° C. overnight to amoisture level below 50 ppm. The additives were dried in a vacuum ovenat 70° C. overnight to remove surface moisture. Containers were madewith the PET, both alone and in combination with varying amounts ofadditives. A lab scale Arburg unit cavity injection molding machine wasused for injection molding. The preforms were blow molded with a SidelSBO ⅔ blow molding machine to make acceptable contour containers. A 24.5g preform made a 500 mL container.

The oxygen transmission rates of the containers were then measured usinga Mocon 2/60 model instrument at 22.2° C. and 50% relative humidity (RH)with the N₂/H₂ (99:1) and air purging rates of 10 mL/min on oppositesides. The results are shown in Table 1. The barrier improvement factor(BIF) was defined as the ratio of the oxygen transmission rate of thepolyester container with additive to the oxygen transmission rate of thepolyester container without additive. TABLE 1 Oxygen transmission rateof 500 mL PET containers O₂ trans- mission Weight IV rate (cc/ OxygenBottle Additive Percent (dL/g) pkg/day) BIF Appearance N/A 0 0.80 0.0461.00 Clear Caffeine 3 0.79 0.0306 1.5 Clear Caffeine 5 0.77 0.0261 1.76Clear

The oxygen BIF of the 500 mL containers improved significantly with theaddition of caffeine to the PET composition, without impairing the IV orclarity of the containers

Example 2

A commercially available polyester container grade resin (Voridian,Kinosport, Tenn.) was prepared, injection molded, and blow molded asdescribed in Example 1. A 26.5 g preform made a 20 oz container.

The bottles were filled with dry ice to achieve an internal pressure of56 psi. The loss rate of CO₂ from the bottles was measured at 22° C. and50% RH using a method described by U.S. Pat. No. 5,473,161, which ishereby incorporated by reference in its entirety. The results are shownin Table 2. The barrier improvement factor (BIF) was defined as theratio of the CO₂ loss rate of the polyester container without additivewas divided by the CO₂ loss rate of the polyester container withadditive. The shelf life of the simulated carbonated soft drink for eachcontainer also was calculated as described by U.S. Pat. No. 5,473,161.TABLE 2 CO₂ Loss of 20 oz PET containers Weight CO₂ shelf life AdditivePercent (Weeks) CO₂ BIF N/A 0 8.7 1.00 Caffeine 0.2 9.2 1.1 Caffeine 7.714.6 1.7 Caffeine 10 17.77 2.0

The carbon dioxide BIF of the 20 oz polyester containers improvedsignificantly with the addition of caffeine to the PET composition,significantly increasing the carbon dioxide shelf life of the polyestercontainers.

Example 3

A commercially available polyester container grade resin (Kosa,Spartanburg, S.C.) was prepared, injection molded, and blow molded asdescribed in Example 1. A 21 g preform made a 12 oz container. The lossrate of CO₂ from the bottles and CO₂ shelf life were determined asdescribed in Example 2. The results are shown in Table 3. TABLE 3 CO₂Loss 12 oz PET containers Weight CO₂ shelf life Additive percent IV(dL/g) (Weeks) CO₂ BIF N/A 0 0.77 8.9 1.0 Caffeine 1 0.77 10.4 1.2Caffeine 3 0.75 12.2 1.4 Caffeine 5 0.77 13.8 1.6

The carbon dioxide BIF of the 12 oz containers improved significantlywith the addition of caffeine to the PET composition, significantlyincreasing the carbon dioxide shelf life of the containers withoutimpairing the IV of the containers.

Example 4

A commercially available polyester container grade resin (Kosa,Spartanburg, S.C.) was combined with caffeine (12 weight percent),pelletized, and dried at 140° C. The mixture and dried PET, prepared asdescribed in Example 1, were combined to achieve a caffeine loadinglevel of 3 weight percent prior to injection molding, as described inExample 1, at a mold temperature setting of 38° C. to make acceptable 21g preforms. The preforms were collected at different times during theinjection molding runs and cut in half so that the colors of thepreforms could be measured with a Hunter lab calorimeter. The resultsare shown in Table 5. Time 0 represents the PET preform withoutcaffeine. Hunter L*,a*,b* color space is a 3-dimensional rectangularcolor space based on the opponent-colors theory and expanded in theyellow region, wherein on the L* (lightness) axis white is 100 and blackis 0, wherein on the a* (red-green) axis red is positive, green isnegative, and neutral is 0; and wherein on the b* (blue-yellow) axisyellow is positive, blue is negative, and neutral is 0. DE* is a measureof the total color difference, calculated by taking the square root ofthe sum of the squares of the changes in L*,a*,b*. TABLE 5 PET PreformColor as a Function of Run Time (hrs) Time (hrs) L* a* B* Haze DE* 079.38 −0.32 2.16 15.84 19.99 0.5 78.66 −0.66 3.38 11.71 20.43 1.5 78.76−0.64 3.57 11.26 20.36 2.5 78.70 −0.68 3.47 11.27 20.40 3.5 78.55 −0.613.5 11.65 20.56 4.5 78.68 −0.60 3.32 11.69 20.40 5.5 78.70 −0.61 3.4011.97 20.39 6.5 78.70 −0.59 3.33 11.96 20.39 7.5 78.89 −0.63 3.64 12.3020.24 8.5 78.95 −0.61 3.26 12.01 20.12 9.5 78.96 −0.62 3.42 11.98 20.1410.5 78.81 −0.62 3.31 12.47 20.27

There is no significant difference between the colors of the preforms atdifferent run times, indicating that the addition of caffeine to the PETcomposition does not significantly impair the preform qualities atdifferent times.

It should be apparent that the foregoing relates only to the preferredembodiments of the present invention and that numerous changes andmodification may be made herein without departing from the spirit andscope of the invention as defined by the following claims andequivalents thereof.

1. A container comprises a polyester composition comprising a polyesterand a purine derivative.
 2. The container of claim 1, wherein the purinederivative comprises a compound having the chemical structure of FormulaI

wherein R₁, R₃, R₅, and R₇, independent of one another, comprise ahydrogen, arylamino, alkoxy, aryloxy, alkenyl, alkynyl, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group; wherein t, t₁, x, x₁, x₂, y, and z,independent of one another, are a single bond or a double bond; whereint′, x′, y′, and z′, independent of one another, are 0 or 1; wherein x″,y″, and w′, independent of one another, are 1 or 2; wherein when x is adouble bond, xi is a single bond; wherein when x₁ is a double bond, xand x₂ are single bonds; wherein when x₂ is a double bond, x₁ and t₁ aresingle bonds; wherein when t is a double bond, t₁ and z are singlebonds; wherein when z is a double bond, t is a single bond; wherein whent, is a double bond, t and x₂ are single bonds; wherein when x is adouble bond, x′ is 0; wherein when x or x₁ is a double bond, x″ is 1;wherein when y is a double bond, y′ is O and y′ is 1; wherein when t ort₁ is a double bond, t′ is 0; wherein when z and t are single bonds, w′is 2; wherein when z or t is a double bond, w′ is 1; wherein when z is adouble bond, z′ is 0; wherein when x, y, or z, independent of oneanother, is a single bond, and x′, y′, or z′, independent of oneanother, is 1; wherein R₂, R₄, and R₆, independent of one another, maybe moieties attached by a single or double bond; wherein when R₂, R₄, orR₆ is a moiety attached by a single bond, R₂, R₄ and R₆, independent ofone another, comprise a hydrogen, hydroxyl, amino, amido, alkylamino,arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo,sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl,phosphonyl, phophinyl, phophoryl, phosphino, thioester, thioether,anhydride, oximno, hydrazino, carbamyl, phosphonic acid, phosphonato, ora straight, chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl,heteroaryl, heterocyclic, or acyl group; wherein when R₂, R₄, or R₆ is amoiety attached by a double bond, R₂, R₄, or R₆, independent of oneanother, comprise oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; R₈ and R₉,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group; and R₁₀comprises a hydrogen, arylamino, alkoxy, aryloxy, alkenyl, alkynyl, or astraight, chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl,heteroaryl, heterocyclic, or acyl group. wherein when x″ is 2, both R₂moieties may be the same or different; wherein when y″ is 2, both R₄moieties may be the same or different; and wherein when w′ is 2, both R₆moieties may be the same or different.
 3. The container of claim 2,wherein the purine derivative of Formula I comprises a compound havingthe chemical structure of Formula II

wherein x, x₁, y, and z are single bonds; wherein x₂ and t are doublebonds; wherein w′, x′, y′, z′, x″, and y″ are 1; and wherein t′ is 0;wherein R₂ and R₄, independent of one another, are moieties attached bya double bond comprising oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; andwherein R₁, R₃, R₅, and R₆, independent of one another, comprise ahydrogen, hydroxyl, amino, amido, alkylamino, arylamino, alkoxy,aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto,imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl,phophoryl, phosphino, thioester, thioether, anhydride, oximno,hydrazino, carbamyl, phosphonic acid, phosphonato, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group.
 4. The container of claim 3, wherein thepurine derivative of Formula II comprises theobromine, a purine dionehaving the chemical structure

wherein R₁ and R₆ are hydrogen; wherein R₂ and R₄ are oxygen; andwherein R₃ and R₅ are methyl.
 5. The container of claim 3, wherein thepurine derivative of Formula II comprises caffeine, a purine dionehaving the chemical structure

wherein R₆ is hydrogen; R₂ and R₄ are oxygen; and R₁, R₃ and R₅ aremethyl.
 6. The container of claim 3, wherein the purine derivative ofFormula II comprises theophylline having the chemical structure

wherein R₂ and R₆ are hydrogen; wherein R₂ and R₄ are oxygen; andwherein R₁ and R₃ and are methyl.
 7. The container of claim 3, whereinthe purine derivative of Formula II comprises xanthine, a purine dionehaving the chemical structure

wherein R₁, R₃, R₅ and R₆ are hydrogen; and R₂ and R₄ are oxygen.
 8. Thecontainer of claim 2, wherein the purine derivative of Formula Icomprises a compound having the chemical structure of Formula III

wherein x, x₁, y, and t, and t₁ are single bonds; wherein x₂ and z aredouble bonds; wherein t′, w′, x′, y′, x″, and y″ are 1; wherein z′ is 0;wherein R₂ and R₄, independent of one another, are moieties attached bya double bond comprising oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; andwherein R₁, R₃, R₆, and R₇, independent of one another, comprise ahydrogen, hydroxyl, amino, amido, alkylamino, arylamino, alkoxy,aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto,imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl,phophoryl, phosphino, thioester, thioether, anhydride, oximno,hydrazino, carbamyl, phosphonic acid, phosphonato, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group.
 9. The container of claim 2, wherein thepurine derivative of Formula I comprises a compound having the chemicalstructure of Formula IV

wherein x, x₁, y, t, t₁, and z are single bonds; wherein x₂ is a doublebond; wherein t′, w′, x′, y′, z′, x″, and y″ are 1; wherein R₂, R₄, andR₆, independent of one another, are moieties attached by a double bondcomprising oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₁, R₃, R₅,and R₇, independent of one another, comprise a hydrogen, hydroxyl,amino, amido, alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl,alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto, imino, sulfonyl,sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl, phophoryl,phosphino, thioester, thioether, anhydride, oximno, hydrazino, carbamyl,phosphonic acid, phosphonato, or a straight, chained, branched, orcyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl, heterocyclic, or acylgroup.
 10. The container of claim 9, wherein the purine derivative ofFormula IV comprises uric acid, a purine dione having the chemicalstructure

wherein R₁, R₃, R₅ and R₇ are hydrogen; and wherein R₂, R₄, and R₆ areoxygen.
 11. The container of claim 2, wherein the purine derivative ofFormula I comprises a compound having the chemical structure of FormulaV

wherein x, x₁, t₁, and z are single bonds; wherein and x₂, t, and y aredouble bonds; wherein w′, x′, z′, x″, and y″ are 1; wherein y′ and t′are 0; wherein R₄ is a moiety attached by a double bond comprisingoxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₁, R₂, R₅, and R₆,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group.
 12. Thecontainer of claim 11, wherein the purine derivative of formula Vcomprises guanine, having the chemical structure

wherein R₁, R₅, and R₆ are hydrogen; wherein R₂ is amino; and wherein R₄is oxygen.
 13. The container of claim 2, wherein the purine derivativeof Formula I comprises a compound having the chemical structure ofFormula VI

wherein x, x₂, y and z are double bonds; wherein x₁, t, and t₁ aresingle bonds; wherein t′, w′, x″, and y″ are 1; wherein x′ and z′ are 0;and wherein R₂, R₆, and R₇ comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group
 14. The containerof claim 13, wherein the purine derivative of Formula VI comprisesadenine, having the chemical structure

wherein R₂, R₆, and R₇ are hydrogen; and wherein R₄ is an amino.
 15. Thecontainer of claim 2, wherein the purine derivative of Formula Icomprises a compound having the chemical structure of Formula VII

wherein x, x₂, and t are double bonds; wherein t₁, x₁, y and z aresingle bonds; wherein w′, y′, z′, x″, and y″ are 1; wherein t′ and x′are 0; wherein R₂ is a moiety attached by a double bond comprisingoxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₃, R₄, R₅, and R₆,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group
 16. The containerof claim 15, wherein the purine derivative of Formula VII comprisesguanine, having the chemical structure

wherein R₃, R₅, and R₆ are hydrogen; wherein R₂ is oxygen; and whereinR₄ is amino.
 17. The container of claim 2, wherein the purine derivativeof Formula I comprises a compound having the chemical structure ofFormula VIII

wherein x₂, y and t are double bonds; wherein x, x₁, t₁, and z aresingle bonds; wherein w′, x′, z′, x″, and y″ are 1; wherein t′ and y′are 0; wherein R₄ is a moiety attached by a double bond comprisingoxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₁, R₂, R₅, and R₆,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group.
 18. Thecontainer of claim 17, wherein the purine derivative of Formula VIIIcomprises 7-methylguanine, having the chemical structure

wherein R₁ and R₆ are hydrogen; wherein R₂ is amino; wherein R₄ isoxygen, and wherein R₅ is methyl.
 19. The container of claim 17, whereinthe purine derivative of Formula VIII comprises thioguanine, having thechemical structure

wherein R₁, R₅, and R₆ are hydrogen; wherein R₂ is amino; and wherein R₄is sulfur.
 20. The container of claim 17, wherein the purine derivativeof Formula VIII comprises 6-mereaptopurine, having the chemicalstructure

wherein R₁, R₂, R₅, and R₆ are hydrogen; and wherein R₄ is sulfur. 21.The container of claim 17, wherein the purine derivative of Formula VIIIcomprises hypoxanthine, having the chemical structure

wherein R₁, R₂, R₅, and R₆ are hydrogen; and wherein R₄ is oxygen. 22.The container of claim 2, wherein the purine derivative of Formulacomprises a compound having the chemical structure of Formula IX

wherein x₁, y, t₁, and z are double bonds; wherein x, x₂, and t aresingle bonds; wherein w′, x′, x″, and y″ are 1; wherein t′, y′, and z′are 0; and wherein R₁, R₂, R₄, and R₆, independent of one another,comprise a hydrogen, hydroxyl, amino, amido, alkylamino, arylamino,alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato,mercapto, imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl,phophinyl, phophoryl, phosphino, thioester, thioether, anhydride,oximno, hydrazino, carbamyl, phosphonic acid, phosphonato, or astraight, chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl,heteroaryl, heterocyclic, or acyl group.
 23. The container of claim 22,wherein the purine derivative of Formula IX comprises 1H-purine, havingthe chemical structure

wherein R₁, R₂, R₄, and R₆ are hydrogen.
 24. The container of claim 22,wherein the purine derivative of Formula IX comprises diaminopurine,having the chemical structure

wherein R₁ and R₆ are hydrogen; and wherein R₂ and R₄ are amino.
 25. Thecontainer of claim 2, wherein the purine derivative of Formula Icomprises 7H-purine, having the chemical structure

wherein x, x₂, y, and t are double bonds; wherein x₁, t₁ and z aresingle bonds; wherein x′, y′, and t′ are 0; wherein x′, y″, z′, and w′are 1; and wherein R₂, R₄, R₅, and R₆ are hydrogen.
 26. The container ofclaim 1, wherein the purine derivative is present in the polyestercomposition in an amount in the range of about 0.2 to about 10 weightpercent of the polyester composition.
 27. The container of claim 1,wherein the purine derivative is present in the polyester composition inan amount in the range of about 3 to about 10 weight percent of thepolyester composition.
 28. The container of claim 1, wherein the purinederivative is present in the polyester composition in an amount in therange of about 3 to about 5 weight percent of the polyester composition.29. The container of claim 1, wherein the polyester comprisespolyethylene terephthalate.
 30. The container of claim 1, wherein thepolyester composition comprises a polytethylene terephthalate) basedcopolymer having less than 20 percent diacid, 10 percent glycolmodification, or both, based on 100 mole percent diacid component and100 mole percent diol component.
 31. A packaged beverage comprising abeverage disposed in the container of claim 1 and a seal for sealing thebeverage in the package.
 32. A polyester composition comprising apolyester and a purine derivative.
 33. The polyester composition ofclaim 32, wherein a) the polyester is present in the polyestercomposition in an amount in the range of about 95 to about 99 weightpercent of the polyester composition; and b) the purine derivative ispresent in the polyester composition in an amount in the range of about0.2 to about 10 weight percent of the polyester composition.
 34. Thepolyester composition of claim 32, wherein the purine derivativecomprises a compound having the chemical structure of Formula I

wherein R₁, R₃, R₅, and R₇, independent of one another, comprise ahydrogen, arylamino, alkoxy, aryloxy, alkenyl, alkynyl, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group; wherein t, t₁, x, x₁, x₂, y, and z,independent of one another, are a single bond or a double bond; whereint′, x′, y′, and z′, independent of one another, are 0 or 1; wherein x″,y″, and w′, independent of one another, are 1 or 2; wherein when x is adouble bond, x₁ is a single bond; wherein when x₁ is a double bond, xand x₂ are single bonds; wherein when x₂ is a double bond, x₁ and t₁ aresingle bonds; wherein when t is a double bond, t₁ and z are singlebonds; wherein when z is a double bond, t is a single bond; wherein whent₁ is a double bond, t and x₂ are single bonds; wherein when x is adouble bond, x′ is 0; wherein when x or x₁ is a double bond, x″ is 1;wherein when y is a double bond, y′ is 0 and y″ is 1; wherein when t ort₁ is a double bond, t′ is 0; wherein when z and t are single bonds, w′is 2; wherein when z or t is a double bond, w′ is 1; wherein when z is adouble bond, z′ is 0; wherein when x, y, or z, independent of oneanother, is a single bond, and x′, y′, or z′, independent of oneanother, is 1; wherein R₂, R₄, and R₆, independent of one another, maybe moieties attached by a single or double bond; wherein when R₂, R₄, orR₆ is a moiety attached by a single bond, R₂, R₄ and R₆, independent ofone another, comprise a hydrogen, hydroxyl, amino, amido, alkylamino,arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo,sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl,phosphonyl, phophinyl, phophoryl, phosphino, thioester, thioether,anhydride, oximno, hydrazino, carbamyl, phosphonic acid, phosphonato, ora straight, chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl,heteroaryl, heterocyclic, or acyl group; wherein when R₂, R₄, or R₆ is amoiety attached by a double bond, R₂, R₄, or R₆, independent of oneanother, comprise oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; R₈ and R₉,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group; and R₁₀comprises a hydrogen, arylamino, alkoxy, aryloxy, alkenyl, alkynyl, or astraight, chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl,heteroaryl, heterocyclic, or acyl group. wherein when x″ is 2, both R₂moieties may be the same or different; wherein when y″ is 2, both R₄moieties may be the same or different; and wherein when w′ is 2, both R₆moieties may be the same or different.
 35. The polyester composition ofclaim 34, wherein the purine derivative of Formula I comprises acompound having the chemical structure of Formula II

wherein x, x₁, y, and z are single bonds; wherein x₂ and t are doublebonds; wherein w′, x′, y′, z′, x″, and y″ are 1; and wherein t′ is 0;wherein R₂ and R₄, independent of one another, are moieties attached bya double bond comprising oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; andwherein R₁, R₃, R₅, and R₆, independent of one another, comprise ahydrogen, hydroxyl, amino, amido, alkylamino, arylamino, alkoxy,aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto,imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl,phophoryl, phosphino, thioester, thioether, anhydride, oximno,hydrazino, carbamyl, phosphonic acid, phosphonato, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group.
 36. The polyester composition of claim 35,wherein the purine derivative of Formula II comprises theobromine, apurine dione having the chemical structure

wherein R₁ and R₆ are hydrogen; wherein R₂ and R₄ are oxygen; andwherein R₃ and R₅ are methyl.
 37. The polyester composition of claim 35,wherein the purine derivative of Formula II comprises caffeine, a purinedione having the chemical structure

wherein R₆ is hydrogen; R₂ and R₄ are oxygen; and R₁, R₃ and R₅ aremethyl.
 38. The polyester composition of claim 35, wherein the purinederivative of Formula II comprises theophylline, a purine dione havingthe chemical structure

wherein R₅ and R₆ are hydrogen; wherein R₂ and R₄ are oxygen; andwherein R₁ and R₃ and are methyl.
 39. The polyester composition of claim35, wherein the purine derivative of Formula II comprises xanthine, apurine dione having the chemical structure

wherein R₁, R₃, R₅ and R₆ are hydrogen; and R₂ and R₄ are oxygen. 40.The polyester composition of claim 34, wherein the purine derivative ofFormula I comprises a compound having the chemical structure of FormulaIII

wherein x, x₁, y, and t, and t₁ are single bonds; wherein x₂ and z aredouble bonds; wherein t′, w′, x′, y′, x″, and y″ are 1; wherein z′ is 0;wherein R₂ and R₄, independent of one another, are moieties attached bya double bond comprising oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; andwherein R₁, R₃, R₆, and R₇, independent of one another, comprise ahydrogen, hydroxyl, amino, amido, alkylamino, arylamino, alkoxy,aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto,imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl,phophoryl, phosphino, thioester, thioether, anhydride, oximno,hydrazino, carbamyl, phosphonic acid, phosphonato, or a straight,chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl,heterocyclic, or acyl group.
 41. The polyester composition of claim 34,wherein the purine derivative of Formula I comprises a compound havingthe chemical structure of Formula IV

wherein x, x₁, y, t, t₁, and z are single bonds; wherein x₂ is a doublebond; wherein t′, w′, x′, y′, z′, x″, and y″ are 1; wherein R₂, R₄, andR₆, independent of one another, are moieties attached by a double bondcomprising oxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₁, R₃, R₅,and R₇, independent of one another, comprise a hydrogen, hydroxyl,amino, amido, alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl,alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto, imino, sulfonyl,sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl, phophoryl,phosphino, thioester, thioether, anhydride, oximno, hydrazino, carbamyl,phosphonic acid, phosphonato, or a straight, chained, branched, orcyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl, heterocyclic, or acylgroup.
 42. The polyester composition of claim 41, wherein the purinederivative of Formula IV comprises uric acid, a purine dione having thechemical structure

wherein R₁, R₃, R₅ and R₇ are hydrogen; and wherein R₂, R₄, and R₆ areoxygen.
 43. The polyester composition of claim 34, wherein the purinederivative of Formula I comprises a compound having the chemicalstructure of Formula V

wherein x, x₁, t₁, and z are single bonds; wherein and x₂, t, and y aredouble bonds; wherein w′, x′, z′, x″, and y″ are 1; wherein y′ and t′are 0; wherein R₄ is a moiety attached by a double bond comprisingoxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₁, R₂, R₅, and R₆,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group.
 44. Thepolyester composition of claim 43, wherein the purine derivative ofFormula V comprises guanine, having the chemical structure

wherein R₁, R₅, and R₆ are hydrogen; wherein R₂ is amino; and wherein R₄is oxygen.
 45. The polyester composition of claim 34, wherein the purinederivative of Formula I comprises a compound having the chemicalstructure of Formula VI

wherein x, x₂, y and z are double bonds; wherein x₁, t, and t₁ aresingle bonds; wherein t′, w′, x″, and y″ are 1; wherein x′, y′, and z′are 0; and wherein R₂, R₄, R₆, and R₇ comprise a hydrogen, hydroxyl,amino, amido, alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl,alkenyl, alkynyl, cyano, sulfo, sulfato, mercapto, imino, sulfonyl,sulfenyl, sulfinyl, sulfamoyl, phosphonyl, phophinyl, phophoryl,phosphino, thioester, thioether, anhydride, oximno, hydrazino, carbamyl,phosphonic acid, phosphonato, or a straight, chained, branched, orcyclic alkyl, alkenyl, alkynyl, aryl, heteroaryl, heterocyclic, or acylgroup.
 46. The polyester composition of claim 45, wherein the purinederivative of Formula VI comprises adenine, having the chemicalstructure

wherein R₂, R₆, and R₇ are hydrogen; and wherein R₄ is an amino.
 47. Thepolyester composition of claim 34, wherein the purine derivative ofFormula I comprises a compound having the chemical structure of FormulaVII

wherein x, x₂, and t are double bonds; wherein t₁, x₁, y and z aresingle bonds; wherein w′, y′, z′, x″, and y″ are 1; wherein t′ and x′are 0; wherein R₂ is a moiety attached by a double bond comprisingoxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₃, R₄, R₅, and R₆,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group
 48. The polyestercomposition of claim 47, wherein the purine derivative of Formula VIIcomprises guanine, having the chemical structure

wherein R₃, R₅, and R₆ are hydrogen; wherein R₂ is oxygen; and whereinR₄ is amino.
 49. The polyester composition of claim 34, wherein thepurine derivative of Formula I comprises a compound having the chemicalstructure of Formula VIII

wherein x₂, y and t are double bonds; wherein x, x₁, t₁, and z aresingle bonds; wherein w′, x′, z′, x″, and y″ are 1; wherein t′ and y′are 0; wherein R₄ is a moiety attached by a double bond comprisingoxygen, sulfur, CR₈R₉, SO₂, or NR₁₀; and wherein R₁, R₂, R₅, and R₆,independent of one another, comprise a hydrogen, hydroxyl, amino, amido,alkylamino, arylamino, alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl,cyano, sulfo, sulfato, mercapto, imino, sulfonyl, sulfenyl, sulfinyl,sulfamoyl, phosphonyl, phophinyl, phophoryl, phosphino, thioester,thioether, anhydride, oximno, hydrazino, carbamyl, phosphonic acid,phosphonato, or a straight, chained, branched, or cyclic alkyl, alkenyl,alkynyl, aryl, heteroaryl, heterocyclic, or acyl group.
 50. Thepolyester composition of claim 49, wherein the purine derivative ofFormula VIII comprises 7-methylguanine, having the chemical structure

wherein R₁ and R₆ are hydrogen; wherein R₂ is amino; wherein R₄ isoxygen, and wherein R₅ is methyl.
 51. The polyester composition of claim49, wherein the purine derivative of Formula VIII comprises thioguanine,having the chemical structure

wherein R₁, R₅, and R₆ are hydrogen; wherein R₂ is amino; and wherein R₄is sulfur.
 52. The polyester composition of claim 49, wherein the purinederivative of Formula VIII comprises 6-mercaptopurine, having thechemical structure

wherein R₁, R₂, R₅, and R₆ are hydrogen; and wherein R₄ is sulfur. 53.The polyester composition of claim 49, wherein the purine derivative ofFormula VIII comprises hypoxanthine, having the chemical structure

wherein R₁, R₂, R₅, and R₆ are hydrogen; and wherein R₄ is oxygen. 54.The polyester composition of claim 34, wherein the purine derivative ofFormula comprises a compound having the chemical structure of Formula IX

wherein x₁, y, t₁, and z are double bonds; wherein x, x₂, and t aresingle bonds; wherein w′, x′, x″, and y″ are 1; wherein t′, y′, and z′are 0; and wherein R₁, R₂, R₄, and R₆, independent of one another,comprise a hydrogen, hydroxyl, amino, amido, alkylamino, arylamino,alkoxy, aryloxy, nitro, acyl, alkenyl, alkynyl, cyano, sulfo, sulfato,mercapto, imino, sulfonyl, sulfenyl, sulfinyl, sulfamoyl, phosphonyl,phophinyl, phophoryl, phosphino, thioester, thioether, anhydride,oximno, hydrazino, carbamyl, phosphonic acid, phosphonato, or astraight, chained, branched, or cyclic alkyl, alkenyl, alkynyl, aryl,heteroaryl, heterocyclic, or acyl group.
 55. The polyester compositionof claim 54, wherein the purine derivative of Formula IX comprises1H-purine, having the chemical structure

wherein R₁, R₂, R₄, and R₆ are hydrogen.
 56. The polyester compositionof claim 54, wherein the purine derivative of Formula IX comprisesdiaminopurine, having the chemical structure

wherein R₁ and R₆ are hydrogen; and wherein R₂ and R₄ are amino.
 57. Thepolyester composition of claim 34, wherein the purine derivative ofFormula I comprises 7H-purine, having the chemical structure

wherein x, x₂, y, and t are double bonds; wherein x₁, t₁ and z aresingle bonds; wherein x′, y′, and t′ are 0; wherein x″, y″, z′, and w′are 1; and wherein R₂, R₄, R₅, and R₆ are hydrogen.
 58. The polyestercomposition of claim 34, wherein the polyester comprises polyethyleneterephthalate.
 59. The polyester composition of claim 34, wherein thepolyester comprises a poly(ethylene terephthalate) based copolymerhaving less than 20 percent diacid, 10 percent glycol modification, orboth, based on 100 mole percent diacid component and 100 mole percentdiol component, and
 60. The polyester composition of claim 34, whereinthe purine derivative is present in the polyester composition in anamount in the range of about 0.2 to about 10 weight percent of thepolyester composition.
 61. The polyester composition of claim 34,wherein the purine derivative is present in the polyester composition inan amount in the range of about 3 to about 10 weight percent of thepolyester composition.
 62. The polyester composition of claim 34,wherein the purine derivative is present in the polyester composition inan amount in the range of about 3 to about 5 weight percent of thepolyester composition.